Currently, there is no easy way to override the DNS servers of PPTP clients in the PPTP configuration section of the WebGUI.
You can, however, override these settings by hand if you really need to change them.
| Backup your router configuration before attempting this change |
$config['pptpd']['dnsserver'] = array('x.x.x.x', 'y.y.y.y');
If you ever need to reverse this change, you may do it like so:
unset($config['pptpd']['dnsserver']);